High Temperature Tolerance CMC & PAC

High Temperature Tolerance CMC & PAC

Product Name: High Temperature Tolerance CMC & PAC
CAS No.: 9004-32-4
HS CODE: 39123100
Other Name: High temperature resistance CMC for Oil drilling fluids
Appearance: White Powder
Grade: Oil drilling grade CMC with ultra-high temperature resistance
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Description

Zibo Hondo Chemical Co., Ltd. is one of the most experienced manufacturers and suppliers of high temperature tolerance cmc & pac in China. Our factory offer high quality products made in China with competitive price. If you have any enquiry about quotation, please feel free to email us.

 

High Temperature Tolerance CMC & PAC for oilfields is a specially modified cellulose derivative designed to cope with the extremely high temperature environment in oil production. In high temperature and high pressure downhole operations, conventional water-soluble polymers are prone to degradation and failure, while high temperature tolerance CMC & PAC has significantly improved thermal stability, salt resistance and rheological properties through molecular structure optimization and process improvement. The high temperature tolerance CMC & PAC is becoming a key additive for oilfield working fluid systems such as drilling fluids and fracturing fluids.These high-temperature-resistant cellulose polymers have been widely validated in deep-well and geothermal drilling, showing stable viscosity retention above 180–200°C and providing lower filtration loss compared with conventional CMC. Their enhanced salt tolerance also supports reliable performance in high-salinity reservoirs, making them essential for modern HPHT (high-pressure high-temperature) oilfield operations.

 

Main Application for High Temperature Tolerance CMC & PAC

  • 1. High temperature tolerance CMC & PAC used in high-temperature deep-well drilling fluid

    In deep formations (such as shale gas and geothermal wells), High temperature tolerance CMC & PAC is compounded with sulfonated phenolic resins, polysulfonates, etc. to maintain the rheological stability of drilling fluids and prevent high-temperature gelation or dilution.By forming a thermally resistant polymer network, HT-CMC/PAC reduces irreversible viscosity loss and mitigates flocculation with divalent cations. Bench tests following API RP 13B-1 style protocols show improved filtration control and stable yield point at elevated temperatures, supporting safer drilling in HT formations.

  • 2. High temperature tolerance CMC & PAC used in fracturing fluid system

    As a thickener for linear gel or cross-linked fracturing fluid, High temperature tolerance CMC & PAC delays gel breaking time in 200°C formations and improves proppant laying efficiency. In unconventional reservoir stimulation (shale, tight gas), HT-CMC/PAC enhances proppant transport and reduces thermal degradation during downhole heating. Field simulations indicate better proppant placement uniformity when HT-CMC/PAC is used as a co-thickener with guar or synthetic gums. Keywords: high-temperature fracturing fluid, proppant transport, thermal stable thickener.

  • 3. High temperature tolerance CMC & PAC used in cementing slurry

    The high temperature tolerance CMC & PAC adjusts the thickening time of cement slurry, reduces free water precipitation at high temperature, and enhances the compressive strength of cement stone.Laboratory cementing tests demonstrate reduced free water and improved early compressive strength in cement cores treated with HT-CMC/PAC blends. This contributes to improved zonal isolation and long-term well integrity under HT conditions.

  • 4. High temperature tolerance CMC & PAC used in water plugging and profile control

    In high-temperature and high-salt reservoirs, High temperature tolerance CMC & PAC is compounded with polymer gel to selectively plug high-permeability layers and improve oil recovery efficiency.HT-CMC/PAC forms a reinforced gel matrix with crosslinkers, offering higher thermal endurance compared with conventional HPAM systems; this enhances profile control and reduces water cut in pilot flood tests.

  • 5. High temperature tolerance CMC & PAC used in geothermal well development

    In geothermal wells above 200°C, Ultra-high temperature resistant CMC is compounded with high-temperature resistant polymers (such as polyetheramine) to form a thermally stable gel system, which effectively prevents well wall collapse.For geothermal and super-critical applications, HT-CMC/PAC blends are subjected to accelerated thermal aging and mechanical shear tests to confirm network integrity; data supports their use in wells exceeding 200°C when formulated with suitable high-temperature co-polymers.

 

Application Solutions for CMC/PAC In Oil drilling industry

 

329401511
 
HTHP drilling solution: Customized CMC/PAC blending to meet filtration loss <10 mL under 200°C.
329400774
 
Geothermal well stability:
Combines high-temp CMC with sulfonated asphalt and SMP for enhanced borehole support.
329700906
 
High-salt reservoir compatibility
Anti-calcium formulation prevents Ca²⁺/Mg²⁺ flocculation.
product-500-428
 
Cementing anti-collapse package
Designed for long-cycle cementing at elevated temperatures.

Core Function

 

  • High temperature tolerance CMC & PAC's rheological regulation function: It could form a network structure in the drilling fluid, control viscosity, ensure suspension of cuttings and clean wellbore.This rheology control is achieved through a tailored molecular weight distribution and controlled degree of substitution (DS), enabling predictable shear-thinning behavior beneficial for both circulation and cuttings transport.

 

  • High temperature tolerance CMC & PAC act as filtrate reducer: It could form a dense filter cake on the well wall, then reduce water infiltration into the formation, and prevent well wall instability.API filtration and HPHT fluid loss tests confirm that HT-CMC/PAC reduces filtrate volumes and forms low-permeability filter cakes under high temperature conditions, minimizing invasion and formation damage.

 

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  • High temperature tolerance CMC & PAC's Lubrication and sand carrying function: Its solution could reduce the friction resistance of the drill bit and improve the proppant carrying capacity of the fracturing fluid.Lower torque and drag in directional drilling cases have been observed where HT-CMC/PAC was used to enhance lubricity; proppant transport efficiency improves due to optimized viscoelastic response at downhole shear rates.

Advantage

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1. Solve the high temperature failure mechanism

High temperature tolerance CMC & PAC is prone to molecular chain breakage and substituent shedding at >120°C, resulting in a sudden drop in solution viscosity and increased filtration loss. High temperature may also trigger flocculation reactions with high-valent metal ions (Ca²⁺, Mg²⁺) in the formation. The ultra-high temperature resistant CMC could well solve the above issue. As its improvement on the molecular chain, it could keep a stable on viscosity under the high temperature environment. It could have a better performance on the filtration loss ability in the deep well and high temperature drilling.Through DS optimization (e.g. DS≥1.0 for selected grades), light crosslinking and molecular-weight tailoring, HT-CMC/PAC retains viscosity and filtration control at temperatures >120°C. Internal HT aging data indicates viscosity retention typically >75–85% after specified aging protocols, evidencing improved thermal resistance versus conventional grades.

2. Modification technology

Optimization of degree of substitution for ultra-high temperature resistant CMC: Increase the degree of carboxymethyl substitution (DS≥1.0) for the high temperature tolerance CMC & PAC, enhance the rigidity of the molecular chain, and reduce high-temperature disentanglement.

Crosslinking modification: Introduce a lightly crosslinked structure (such as epichlorohydrin crosslinking) to form a three-dimensional network to resist thermal degradation.

Molecular weight control for the Ultra-high temperature resistant CMC: Adjust the molecular weight distribution through oxidative degradation or enzymatic pretreatment to balance high-temperature viscosity and solubility. With this coordinate, improve the performance for the high temperature tolerance CMC.Our manufacturing control includes batch COA reporting of DS, viscosity, moisture and HT aging performance; traceable production records and pilot HT test data are available to qualified engineering buyers upon request.

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Specification

 

Spec.

Standard

Appearance

White or yellowish powder

Starch

None

Moisture

≤10.0%

DS

0.9-1.2

Filtration loss (API)

API standard

Purity

Technical or high purity

pH

7.0~10.0

Viscosity (1% solution)

10-3500 mPa·s

 

Quality Control Section

 

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Standardized, controlled, and trustworthy
  • Raw Material Control: Only select high-purity cellulose with controlled ash and fiber content to ensure consistent molecular substitution.
  • Production Process Control: Automated reaction monitoring ensures stable DS (0.9–1.2) and uniform polymer distribution.
  • In-Process Testing: Viscosity, pH, moisture, substitution uniformity, and filtration-loss performance are tested every batch.
  • Pre-Shipment Quality Assurance: COA provided with every shipment; third-party SGS/Intertek testing available on request.

 

Packing & Storage

 

Storage:

1. Ultra high temperature resistant Carboxymethyl cellulose should store in a cool, dry, clean, ventilated environment. Temperature Max. 70℃, with relative humidity ≤80%.

Storage:

2. The CMC for pharmaceutical and food grade should not be put together with the toxic substance and harmful substance or substance with peculiar smell during transportation and storage.

Storage:

3. Since the date of production, a preservation period of high temperature resistance sodium CMC should not exceed 4 years for the industrial product and 2 years for the CMC in pharmaceutical and food industry.

Storage:

4. The ultra-high temperature resistance CMC should be prevented from water and package bag damaging during transportation.

Packing:
 

25kg kraft paper bag with PE inner, or as clients request.

PAC-R

Why Choose Us

 

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  • 15+ years of experience in cellulose chemistry and oilfield additives
  • Stable supply capacity with professional export support
  • Customizable viscosity levels & high-temperature performance parameters
  • Full technical documents: COA, MSDS, TDS, API test results
  • Professional technical support for HTHP drilling and geothermal fields

 

Summary

 

High temperature tolerance CMC & PAC has solved the performance bottleneck of traditional cellulose derivatives in high temperature oil field environment through molecular structure optimization and composite modification, and the high temperature tolerance CMC & PAC has become an important auxiliary agent in deep well, ultra-deep well and unconventional oil and gas production. Its development is closely centered on the extreme conditions of oil field operations, and will further evolve towards multifunctionality and intelligence in the future.

 

FAQ

Q1: What is the maximum temperature your CMC/PAC can withstand?
Our upgraded high-temperature CMC & PAC maintains functionality up to 200°C, depending on formulation.

 

Q2: Is it compatible with brine, CaCl, or high-salt drilling fluids?
Yes. The product is designed with anti-calcium mechanisms to prevent flocculation or viscosity loss.

 

Q3: Can this product replace standard PAC/CMC?
In high-temperature wells → Yes, strongly recommended
In low-temperature wells → Standard PAC/CMC may be sufficient

 

Q4: Can you provide technical testing support?
Yes, we offer HTHP tests, aging tests, and compatibility evaluations.

 

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